劉建輝, 男, 曾經(jīng)系統(tǒng)研究了有機(jī)硅化物在五員雜環(huán)化合物中的應(yīng)用(包括多取代吡咯的合成方法學(xué)、高張力五員雜環(huán)3,4-二去氫吡咯的捕獲)，單有機(jī)錫化合物試劑在碳碳偶聯(lián)反應(yīng)中的應(yīng)用，含吡咯與吡啶的大環(huán)的合成。現(xiàn)在在大連理工大學(xué)精細(xì)化工國(guó)家重點(diǎn)實(shí)驗(yàn)室工作, 從事電化學(xué)發(fā)光材料與新型氫能源的研究。
為國(guó)際重要學(xué)術(shù)期刊(Inorg.Chem., J.Med.Chem.,Tetrahedron, Tetrahedron Lett.)的論文審稿人。
人物經(jīng)歷
1961年2月出生于湖北武漢。1983年畢業(yè)于蘭州大學(xué)藥學(xué)系，畢業(yè)后在蘭醫(yī)附屬一院藥劑科工作，1988年考入北京協(xié)和醫(yī)學(xué)院－清華大學(xué)醫(yī)學(xué)部（中國(guó)醫(yī)學(xué)科學(xué)院）醫(yī)藥生物技術(shù)研究所，專業(yè)為微生物藥物學(xué)。在抗生素專家郭惠元教授指導(dǎo)下，進(jìn)行諾類抗菌劑的合成與構(gòu)效關(guān)系研究。碩士畢業(yè)后，在首都醫(yī)科大學(xué)化學(xué)教研室工作。1996年2月公派到香港中文大學(xué)化學(xué)系攻讀博士學(xué)位，在中科院院士黃乃正教授的指導(dǎo)下，從事有機(jī)合成方法學(xué)的研究。獲得博士學(xué)位后由黃乃正教授推薦，于1999年12月被法國(guó)國(guó)家科學(xué)研究中心聘為研究員，在其下屬的波爾多第一大學(xué)有機(jī)與金屬有機(jī)實(shí)驗(yàn)室從事有機(jī)錫化合物的研究，為期10個(gè)月。從2000年11月至2002年10月，先后在杜伊斯堡-埃森大學(xué)大學(xué)和波鴻大學(xué)做博士后，在G. Dyker教授的研究組從事雜環(huán)化合物的合成研究。
研究方向
1.有機(jī)合成方法學(xué)及其在功能分子構(gòu)建中的應(yīng)用;
2.與光系統(tǒng)II相關(guān)的釋氧中心的化學(xué)模擬, 卟啉類化合物 與Corroles金屬配位化合物的研究;
3.含硫過(guò)渡金屬絡(luò)合物的研究, 氫酶活性中心的化學(xué)模擬;
4.精細(xì)化工產(chǎn)品的合成 (藥物及其中間體, 農(nóng)藥, 染料和發(fā)光材料等).
碩博研究方向
1.光體系II的化學(xué)模擬;
2.唯鐵氫化酶活性中心的模擬;
3.Porphyrins與Corroles化合物的合成與性能;
4.片螺素及其非天然類似物的合成與抗腫瘤活性。
主要貢獻(xiàn)
1.Gerald Dyker, Dirk Hildebrandt, Jianhui Liu, Klaus Merz
Domino Process with Isobenzopyrylium cation Intermediate
Angew. Chem., Int. Ed. 2003, 42, 4399-4402
2. Xien Liu, Jianhui Liu, Kun Jin, Xichuan Yang, Qinji Peng, Licheng Sun
Synthesis, Characterization and Some Properties of 酰胺linked 卟啉ruthenium(II) Tris(bipyridine) Cmplexes
Tetrahedron 2005, 61, 5655-5662
3. Shi Jiang, Jianhui Liu, Licheng Sun
A 呋喃containing diiron azadithiolate hexacarbonyl complex with unusual lower 催化 proton reduction potential
Inorg. Chem. Commun. 2006, 9(3), 290-2
4. Weiming Gao, Jianhui Liu, Changneng Chen, Linhong Weng, Kun Jin, Bjorn Akermark, Licheng Sun
Synthesis, structures and electrochemistry properties of amino-derivatives of diiron azadithiolates as active site models of Fe-only hydrogenase
Inorg. Chim. Acta 2006, 359, 1071-1080
5. Xien Liu, Jianhui Liu, Jingxi pan, Ruikui Chen, Yong Na, Weiming Gao, Licheng Sun
A Novel Ruthenium(II) Tris(bipyridine)-鋅 卟啉錸 Carbonyl Triad: Synthesis and Optical Properties
Tetrahedron 2006, 62, 3674-3680
6. Wei Zhang, Jianhui Liu, Kun Jin, Licheng Sun
Synthesis of Some New 4-Substituted-3, 5-胺醚(2-Pyridyl)-1H-吡唑
J. Heterocyclic Chem. 2006, 43, 1669-1672
7. Minna Li, Jianhui Liu, Changzhi Zhao, Licheng Sun
Aryl-Diamide Centered Binuclear Ruthenium (II) tris(bipyridine) Complexes: Synthesis, Photophysical, Electrochemical and Electrochemiluminescence Properties
J. Organomet. Chem. 2006, 691, 4189-4195
8. Weiming Gao, Jianhui Liu, Bjorn Akermark, Licheng Sun
Bidentate 磷化氫 配體 based Fe2S2containing macromolecules: synthesis, characterization, and 催化 electrochemical 氫 production
Inorg. Chem., 2006, 45, 9169-9171
9. Yan Gao, Jianhui Liu, Mei Wang, Yong Na, Bjorn Akermark, Licheng Sun
錳 corrole complexes as catalysts for H?O oxidation
J. 卟啉類化合物 Phthalocyanines, 2006, 10, 403
10. Jianhui Liu, Enrico Muth, Ulrich Flke, Gerald Henkel, Klaus Merz, Janelle Sauvageau, Erik Schwake, Gerald Dyker
Alkylation of Arenes with 芐型 and Propargylic Alcohols -- Classical versus Fancy Catalysts
Adv. Synth. Catal. 2006, 348, 456-462
11. Shi Jiang, Jianhui Liu, Yu Shi, Zhen Wang, Bjorn Akermark, Licheng Sun
Preparation, Characteristics and 晶體 Structures of Novel N-Heterocyclic 卡賓 Substituted 呋喃 and 吡啶Containing Azadithiolate Fe-S Complexes
多面體 2007, 26(7), 1499-1504
12. Yan Gao, Jianhui Liu, Mei Wang, Yong Na, Bjorn Akermark, Licheng Sun
Synthesis and characterization of 錳 and copper corrole 氧雜蒽 complexes as catalysts for H?O oxidation
Tetrahedron 2007, 63, 1987
13. Zhen Wang, Jianhui Liu, Chengjiang He, Shi Jiang, Bjorn Akermark, Licheng Sun
Diiron Azadithiolates with Hydrophilic Phosphatriaza-adamantane Ligand as Iron-Only Hydrogenase Active Site Models: Synthesis, Structure, and Electrochemical Study
Inorg. Chim. Acta 2006, 360, 2411-2419
14. Weiming Gao, Jianhui Liu, Bjorn Akermark, Licheng Sun
Facile and Highly Efficient Light-induced pr3/CO Ligand Exchange: A Novel Approach to the Synthesis of [(μ-SCH2NnPrCH2S)Fe2(CO)4(PR3)2]
J. Organomet. Chem. 2007, 692, 1579-1583
15. Weiming Gao, Jesper Ekstrom, Jianhui Liu, Changneng Chen, Lars Eriksson, Linhong Weng, Bjorn Akermark, Licheng Sun
Binuclear Iron-硫 Complexes with Bidentate 磷化氫 Ligands as Active Site Models of Fe-Hydrogenase and Their 催化 Proton Reduction
Inorg. Chem., 2007, 46, 1981-1991
16. Shi Jiang,Jianhui Liu, Yu Shi,Zhen Wang, Bjorn Akermark, Licheng Sun
Fe-S complexes containing five-membered heterocycles: novel models for the active site of hydrogenases with unusual low reduction potential
Dalton Trans., 2007, 896-902
17. Ming Xia, Jianhui Liu, Yan Gao, Bjorn Akermark, Licheng Sun
Synthesis, and Photophysical and Electrochemical Study of Tyrosine Covalently Linked to High Valent Copper (III) and 錳 (IV) Complexes
Helv. Chim. Acta, 2007, 90, 553-561
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