陳艷霞,女,1971年9月出生于湖南省,本科、碩士、博士均畢業于廈門大學,現任中國科學技術大學化學物理系和合肥微尺度物質科學國家實驗室教授、博士生導師,主要研究表面電化學、光譜電化學和電催化。
學習和工作經歷
1989.9 – 1993.7,廈門大學化學化工學院,學士 物理化學專業;
1993.9 – 1995.7,廈門大學化學系,碩士學位,物理化學專業;
1995.9 – 1998.10,廈門大學化學系,博士學位,物理化學專業;
1998.11 – 1999.2,廈門大學化學系,科研助手,物理化學專業;
1999.3 – 2000.12,杜塞爾多夫大學表面和凝固態材料研究所(A. Otto教授),洪堡獎學金,博士后,利用衰減全內反射拉曼光譜研究單晶銅表面物種的吸附,了解表面增強拉曼效應和金屬表面粗糙度的關系;
2001.1 – 2001.12,慕尼黑工業大學物理系界面和能量轉換研究所(U. Stimming教授),博士后,開發、表征優化氫氧燃料電池、直接甲醇燃料電池的膜電極列陣(Membrane Electrode Assemblies),以降低催化劑用量同時提高電池的效率,延長電池的壽命;
2002.1 – 2002.3,北海道大學催化研究中心界面和光譜電化學實驗室(M. Osawa教授),日本北海道大學日本文部科學省中核集團機構COE研究員,主要任務:利用表面增強紅外光譜研究甲醇在鉑電極上的陽極氧化;
2002.4 – 2006.12,烏爾姆大學表面化學和催化研究所 (R. J. Behm教授) 博士后,電化學原位紅外光譜和電化學在線質譜研究燃料電池相關的電催化反應;
2007.1 – 至今,中國科技大學化學物理系,合肥微尺度物質科學國家實室,教授,博士生導師,譜學電化學在電催化中的應用。
研究方向
表面電化學、光譜電化學和電催化,著重于電化學界面結構、燃料電池以及生物電化學相關的電催化反應機理和動力學的基礎研究以及相關研究技術的開發。
在研項目
1.面向車用燃料電池的納米-介觀-宏觀多級結構的電催化體系的研究, 973 重大科學研究計劃子課題: 結構明確的高活性電催化劑納米結構基元的合成(編號2015CB932300,2014-2019)
2.Pt系單晶電極上氧還原反應超電勢的起源研究, 國家自然基金面上項目 (編號:21473175, 2015-2018)
3. 等離子基元增強拉曼光譜儀器的研發與應用子課題,PERS在電化學基礎研究中的應用,國家重大科學儀器設備開發專項(編號:2011YQ03012416 2012-2016)
4. 電化學導數質譜與紅外光譜聯用技術及其在燃料電池電催化中的應用, 國家自然基金面上項目 (編號:21273215, 2013-2016)
已完成項目
1. 基于分子和分子體系的量子調控子課題,電極過程的量子調控, 973 重大科學研究計劃 (編號2010CB923302,2009-2014)
2.臺灣中國科技大學海外優秀留學人才啟動基金(2007-2009)
3. 在可控的溫度及傳質下甲醇氧化的電化學原位紅外光譜研究, 國家中華人民共和國國家自然科學基金委員會面上項目(項目批準號:20773116, 2008-2010)
4. 低鉑擔載甲醇氧化電催化劑結構-性能關系研究, 德國洪堡基金會回國后續支持項目(2007-2009)
5. 用于甲醇陽極氧化的低維納米復合電催化劑的制備及性能表征, 廈門大學固體表面物理國家重點實驗室開放課題 (2008-2009)
6. 中國科院百人計劃(2009-2011)
7. 石墨烯上鈉米粒子的構筑及其電催化活性研究, 廈門大學固體表面物理國家重點實驗室開放課題(2010-2011)
8. 譜學電化學在電催化中的應用, 教育部留學回國人員啟動基金(2010-2012)
9. 鉑基氧還原催化劑性能改善機理研究, 國家中華人民共和國國家自然科學基金委員會面上項目(項目批準號:21073176,2011-2013).
獲獎情況
1. 電化學青年獎,中國電化學會,2011.10
2. 青年研究獎學金,德國洪堡基金會, 1999. 7- 2000.12, 2002.7-2002.9
3. 日本文部省COE獎學金
4. 中國科學院星”百人計劃”擇優支持
5. 北海道大學訪問教授
發表的學術論文及專著
Papers published in 2014
1. The Effect of 乙醇 Concentration on the 質量 Signal of CO2 Detected by Differential Mass Spectrometry
Wei Chen; Qian Tao; Jun Cai; Yan Xia Chen
Electrochemistry Communications, 2014,48,10.
2. On the Origin of the Errors of ik as Estimated from K-L Equation in Rotating Disk Electrode System
Wei Chen; Lingwen Liao; Zhengda He; Yanxia Chen
Journal of Electrochemistry
3. The Preparation of Surfactant-free Pt and PtRu Nanoparticles with high Activity for 甲醇 Oxidation
Yao Yao, Jun Cai, Yong Li Zheng, Yan-Xia Chen
Chinese Journal Of Chemical Physics, 2014
4. Methanol Oxidation at Pt and PtRu Electrodes, a Study by Combined in-situ Infrared Spectroscopy and Differential Electrochemical 質量 Spectrometry (Acceped)
Qian Tao, Wei Chen, Yao Yao, Ammar Bin Yousaf ,Yan-Xia Chen
Chinese Journal Of Chemical Physics, 2014
5. A Kinetics Study on O2 Adsorption and OHad Desorption at Pt(111), Its Implication to 氧 Reduction Reaction Kinetics (Acceped)
Fan Yang,Ling Wen Liao,Ming Fang Li,越南盾 Mei,Yan-Xia Chen
Chinese Journal Of Chemical Physics, 2014
6. Mechanistic and Kinetic Implications on ORR at Au(100) Electrode, pH, 溫度 and H-D kinetic Isotope effects
D. Mei, Z. D. He, Y. L. Zheng, D. C. Jiang, Y.-X. Chen
Phys. Chem. Chem. Phys, DOI:10.1039/C4CP00257A
7. Redox Reaction of HydroGen.G Peroxide at Au(100) Electrode, Its Implication to 氧 Reduction Kinetics
Zheng, Y; Mei, D; Chen, Y; Ye, S.
Electrochem. Commun,2014, 39,19.
8. Interaction of C1 Molecules with a Pt Electrode at Open Circuit Potential: A Combined Infrared and 質量 Spectroscopic Study
Q. Tao, 櫻狼 Zheng, D.-C. Jiang, Y.-X. Chen,Z. Jusys and R. J. Behm
J. Phys. Chem. C, 2014, 118, 6799
9. Electrodeposition of silver on stepped 鉑 electrode surfaces with (100)-oriented terraces: Generation of confined reaction sites
J. Xu, A.-E.-Aziz, A. A.-E.l-Latif, Y.-X. Chen, H. Baltruschat
J. 銀金礦anal. Chem.,2014, 716, 93
10. Modeling of the Potential Oscillation during Galvanostatic Electrooxidation of Formic Acid at 鉑 Electrode
越南盾 Mei, Zheng-Da He, Dao Chuan Jiang, Jun Cai and Yan-Xia Chen
J. Phys. Chem. C, 2014,118,6335.
11. 甲醇及甲酸在模型單晶鉑電極上電催化氧化機理及動力學的研究
徐杰, 江道傳,梅東, 何政達,陳艷霞
電化學
Papers published in 2013
1. Kinetic Implication from 溫度 effect on HydroGen.G 翼豪陸神 Reaction at Ag Electrode
Jing Kang, Chu-Hong Lin, Yao Yao and Yan-Xia Chen
Chinese Journal Of Chemical Physics, 2013.27.63
2. 鉑基催化劑上的氧還原
李明芳, 廖鈴文, 楊帆, 姚瑤, 陳艷霞
電催化, 化工出版社, 第7章, 2013
3. Potential Dependence of 氰化物 Adsorption at Pt Electrode in Acidic Solution: An Electrochemical in-situ Infrared Spectroscopic Study
Shao Xiong Liu, Yong Li Zheng, Jie Xu, Jun Cai, Wen Hua Zhang, Jin Long Yang, Yan Xia Chen*
J. Physical 化學 C, 2013, 117, 15562.
4. pH Effect on OxyGen.G Reduction Reaction at Pt(111) Electrode
Ming Fang Li, Ling Wen Liao,Dao Fu Yuan, 越南盾 Mei, Yan-Xia Chen*
Electrochim. Acta, 2013,110,780.
5. On the Mechanism of the Direct Pathway for Formic Acid Oxidation at Pt(111) Electrode
J. Xu, 三角洲特種部隊1 Yuan, F.Yang, D. Mei, Z. B. Zhang and Y. X. Chen
Phys. Chem. Chem. Phys., 2013, 15 (12), 4367.
6. Density functional theory study on the adsorption and decomposition of the formic acid catalyzed by highly active mushroom-like Au@Pd@Pt 三角座metallic nanoparticles
S. Duan,YF系列火箭發動機 Ji,帕塔查雅·平莎莫 Fang,Y. X. Chen,X. Xu,Y. Luoand Z.-Q. Tian
Phys. Chem. Chem. Phys., 2013, 15 (13), 4625.
7. Electrode Reaction Induced pH change at the Pt Electrode/Electrolyte Interface and its Impact on Electrode Processes
L. W. Liao, M. F. Li, J. Kang, D. Chen, Y. X. Chen and S. Ye
J. Electroanal. Chem. 2013, 688, 207.
8. The Effect of Catalyst Loading on the Evaluation of Kinetic Parameters of Gas Electrode Reactions using Thin Film Rotating Disk Electrode Method
L. W. Liao, D. Chen, M. F. Li, Y. L. Zheng, J. Kang, Y. X. Chen,
SCIENTIA SINICA Chimica, 2013,43,178.
9. A Revisit to the Role of Bridge-adsorbed Formate in the Electrocatalytic Oxidation of Formic Acid at Pt Electrodes
J. Xu; D. Mei; D. F. Yuan; Z. B. Zhang; S. X. Liu; Y. X. Chen
Chinese Journal Of Chemical Physics, 2013, 26(3), 321.
10. The Role of Bridge-bonded Formate in Formic acid Dehydration to CO at Pt Electrode: An Electrochemial in situ Infrared Spectroscopic Study
Z. B. Zhang, J.Xu, J. Kang and Y. X. Chen,
Chinese Journal Of Chemical Physics, 2013, 26(4),471.
11. OxyGen.G Reduction Reaction on Glycin Modified Pt(111) Electrode
M. F. Li, J. Kang, L. W. Liao, Y. X. Chen and S. Ye
Journal of Electrochemistry, 2013, 19, 1.
12. Determination of the Isotherm for Acetate and Formate Adsorption at Pt(111) Electrode by 500米口徑球面射電望遠鏡 Scan Voltammetry
J. Xu, C.H. Lin, D. Mei, Z. B. Zhang, D. F. Yuan and Y. X. Chen
Chinese Journal Of Chemical Physics, 2013,26(2),191.
Papers published in 2012
1. 溫度 Effect on 氫 翼豪陸神 Reaction at Au Electrode
Z. Q. Tang; L. W. Liao; Y. L. Zheng; J. Kang; Y. X. Chen
Chinese Journal Of Chemical Physics, 2012, 25,469.
2. Control over the branched structures of 鉑 nanocrystals for electrocatalytic applications
L. Ma,C. M. Wang,M. Gong, L. W. Liao, R. Long, J. G. Wang, D. Wu, W. Zhong, M. J. Kim, Y. X. Chen,Y. Xie, and Y. J. Xiong,
ACS Nano, 2012, 69797.
3. Polyoxometalates Immobilized in Ordered Mesoporous 碳 Nitride as Highly Efficient 液態水 Oxidation Catalysts
J. Wu, L. W. Liao, W. S. Yan, Y. Xue, Y. F. Sun, X. Yan, Y. X. Chen, and Y. Xie,
ChemSusChem,2012, 5,1207.
Papers published in 2011
1. The Kinetics of CO Pathway in 甲醇 Oxidation at Pt Electrodes, a Quantitative Study by ATR-FTIR Spectroscopy
L.W. Liao, S. X. Liu, Q. Tiao, B. Gen.G,P. Zhang, C. M. Wang, Y.-X. Chen and S. Ye,
Phys.Chem. Chem. Phys., 2011, 13, 9725.
2. A method for kinetic study of 甲醇 oxidation at Pt electrodes by electrochemical in situ infrared spectroscopy
L.W. Liao, S. X. Liu, Q. Tiao, B. Gen.G,P. Zhang, C. M. Wang, Y.-X. Chen and S. Ye,
J. 銀金礦anal. Chem., 2011, 650, 233.
3. Determining the Active surface Area of Various Pt Electrodes with Different Roughness and Dispersion
Dong Chen, Qian Tao, Ling Wen Liao, Shao Xiong Liu, Yan-Xia Chen and Shen Ye,
Electrocatalysis, 2011.2.207
4. 室溫下Pt電極上CO的脫附機理研究
劉少雄, 康婧, 耿斌, 陶騫, 陳艷霞
中國科學,化學,2011, 41, 1582.
5. 不同pH值下多晶Au電極上的氧還原反應
中國科學,化學, 2011,41, 1777.
6. Pd/Pt二元合金電極的制備及其氧還原性能研究
高等學?;瘜W學報, 2011,32, 1144.
7. Electrochemistry of ABTS at Glassy 碳 Electrodes
Han Zeng, Zhi-qiang Tang, Ling-wen Liao, Jing Kang, Yan-xia Chen
Chinese J. Chemical Physics, 2011, 24, 653.
Papers published before 2011
1. 溫度 effects on CO Adsorption/Desorption at Pt Film Electrodes: An Electrochemical in-situ Infrared Spectroscopic Study
B. Gen.G, J. Cai, S. Liang, S. X. Liu, M.F. Li and Y.-X. Chen,
Phys. Chem. Chem. Phys., 2010, 12, 10888 - 10895
2. Potential-Dependent Chemisorption of 碳 Monoxide at a Gold Core―鉑 Shell Nanoparticle Electrode: A Combined Study by Electrochemical in s國際科技大學 surfaceEnhanced Raman Spectroscopy and Density Functional Theory
Pu Zhang, Jun Cai, Yan-Xia Chen, Zhi-Qiang Tang, Dong Chen, JinLong Yang,De-Yin Wu, Bin Ren and Zhong-Qun Tian,
J. Phys. Chem. C, 2010, 114, 403–411
3. Oxidation of 碳 Supports at Fuel Cell Cathodes: Differential Electrochemical 質量 Spectrometric Study
M.F. Li, Q. Tao, L. W. Liao, J. Xu, J. Cai and Y. X. Chen,
Chinese J. Chemical Physics, 2010, 4, 442-446
4. Determination of the Real surface Area of 鈀 Electrode
L.-L. Fang, Q. Tao, M.-F. Li, L.-W. Liao, D. Chen and Y.-X. Chen,
Chinese J. Chemical Physics, 2010, 5, 543.
曾涵,廖鈴文,李明芳,陶騫,康婧,陳艷霞,
物理化學學報,2010, 26, 3217。
梁桑梓,劉少雄,廖玲文,陶騫,康婧,陳艷霞,
電化學,2010,16,324
7. 溫度 Programmed Desorption – An Application to Kinetic Studies of CO Desorption at Electrochemical Interfaces
Bin Gen.G, Jun Cai, Shao-Xiong Liu, Pu Zhang, Zhi-Qiang Tang, Dong Chen, Qian Tao,Yan-Xia Chen and Shou-Zhong Zou,
J. Phys. Chem. C, 2009, 113, 20152–20155.
8. An Electrochemical in Situ surfaceEnhanced Raman Spectroscopic Study of 碳 Monoxide Chemisorption at a Gold Core-鉑 Shell Nanoparticle Electrode with a FLOW Cell
Pu Zhang, Yan-Xia Chen, Jun Cai, Sang-Zi Liang, Jian-Feng Li, An Wang, Bin Ren and Zhong-Qun Tian
J. Phys. Chem. C, 2009,113(40): 17518-17526.
9. The Mechanism and Kinetics of 氰化物Assisted CO Desorption from Pt Electrodes: an Infrared Spectroscopic Study
Bin Gen.G, Shaoxiong Liu, Jun Cai, Sangzi Liang, and Yan-Xia Chen,
J. Phys. Chem. C, 2009, 113, 10326.
10. A Thermostatic Cell with Gas Diffusion Electrode for OxyGen.G Reduction Reaction under Fuel Cell Relevant Conditions
Yan-Xia Chen, Ming-Fang Li, Ling-Wen Liao, Jie Xu, Shen Ye,
Electrochem. Commun., 2009,11,1434
11. Potential-Induced COad Island Formation on a 鉑 Thin-Film Electrode in the H-upd Potential Region
Yan-Xia Chen, Martin Heinen, Zenonas Jusys, and Rolf Juergen Behm,
J. Phys. Chem. C, 2007, 111, 435.
12. Kinetic Isotope Effects in Complex Reaction Networks: Formic Acid 銀金礦Oxidation
Yan-Xia Chen, Martin Heinen, Zenonas Jusys, and Rolf Juergen Behm,
ChemPhysChem, 2007, 8, 380 – 385.
13. Room 溫度 COad Desorption/Exchange Kinetics on Pt Electrodes—A Combined In Situ IR and 質量 Spectrometry Study
Martin Heinen, Yan-Xia Chen, Zenonas Jusys, and Rolf Juergen Behm,
ChemPhysChem, 2007, 8, 2484 – 2489.
14. CO adsorption kinetics and adlayer build-up studied by combined ATR-FTIR spectroscopy and on-line DEMS under continuous flow conditions
Martin Heinen, Yan-Xia Chen, Zenonas Jusys, and Rolf Juergen Behm,
Electrochmica Acta, 2007, 53,1279.
15.in situ ATR-FTIRS coupled with on-line DEMS under controlled 質量 transport conditions—A novel tool for electrocatalytic reaction studies
Martin Heinen, Yan-Xia Chen, Zenonas Jusys, and Rolf Juergen Behm,
Electrochmica Acta, 2007, 52,5634
16. Kinetics and Mechanism of Formic Acid 銀金礦oxidation – Spectro-Electrochemical Studies in a Novel Flow Cell Configuration,
Yan-Xia Chen, Martin Heinen, Zenonas Jusys, and Rolf Juergen Behm,
Angewandte Chemie, Int. Edition, 2006, 45, 981.
17. Bridge-Bonded Formate: Activeintermediate or Spectator 物種 in Formic Acid Oxidation on a Pt Film Electrode
Yan-Xia Chen, Martin Heinen, Zenonas Jusys, and Rolf Juergen Behm,
Langmuir, 2006, 22, 10399.
18. Application of in-situ Attenuated Total Reflection-Fourier Transform Infrared Spectroscopy for the Understanding of Complex Reaction Mechanism and Kinetics: Formic Acid Oxidation on a Pt Film Electrode at Elevated Temperatures,
Yan-Xia Chen, Martin Heinen, Zenonas Jusys, and Rolf Juergen Behm,
J. Phys. Chem. B, 2006 110(19): 9534-9544.
19. Electronic effects in SERS by liquid 液態水
Yan-Xia Chen and Andreas 侯國玉,
J. Raman SpectroSC, 2005, 36, 736.
20. CO2 reduction on Pt electrocatalysts and its impact on H2 oxidation in CO2 containing fuel cell feed gas - A combined in-situ infrared spectroscopy, 質量 spectrometry and fuel cell 表演 study
Smolinka T., Heinen M., Chen Y.X., Jusys Z., Lehnert W., and Behm R.J.,
Electrochimica Acta, 2005, 50, 5189.
21. Formate, an Active Intermediate for Direct Oxidation of 甲醇 on Pt Electrode.
Chen Y. X., Miki A., Ye S.,Sakai H. and Osawa M.:
Journal of American Chemical Society, 125 (2003), 3680.
22. On the "氯化物 activation" in SERS and single 摩爾cule SERS.
Otto A., Bruckbauer A., Chen Y. X.,
Journal of Molecular Structure, 2003, 662, 501.
23. The charge transfer effect of SERS induced by the electrochemical 氫 evolution reaction.
F. M. Liu; Q. Han; Y. X. Chen; Q. L. Zhong; B. Ren; Z. Q. Tian,
Electrochemistry, 2001, 7(1), 74-77.
24. SERS studies of Electrode/electrolyte interfacial 液態水 II. Librations of water and electrochemical 氫 evolution reaction
Chen Y. X., Zou S. Z., Huang K. Q. and Tian Z. Q.,
Journal of Raman Spectroscopy, 1998,249,749.
25.in Situ Raman Spectroscopic Study of the Oxidation and Reduction of Ag Electrode in Na2SO4 solution.
Chen Y. X., Huang K. Q. and Tian Z. Q.:
Electrochemistry,1998,4(2) 135.
26. SERS studies on electrode/electrolyte interfacial 液態水---I. Ion effects in the negative potential region
Zou S. Z., Chen Y. X., 市道真央 B.W., Ren B. and Tian Z. Q.:
Journal of Electroanalytical 化學,1997,24, 19-25.
27. Extending ecsTM Studies to Polycrystalline Electrode Surfaces with Atomic Resolution.
Shi C. H., Cai X. W., Chen Y. X., Tian Z. Q. and Mao B. W.:
Acta Physico-Chimica Sinica, 1997,13(12) 1061-1064
28. SERS Studies of Electrode/Electrolyte Interfaces I. Cu/1.0 M Na2SO4 and NaCl solution.
Chen Y. X., Huang K. Q. and Tian Z. Q.:
Chinese Journal of Light Scattering,1997,9(2-3), 289-291.
29. SERS Studies of Electrode/Electrolyte Interfaces II. Ag/MgSO4 System? A Possible Method Measuring Interfacial pH.
Chen Y. X., Huang K. Q. and Tian Z. Q.:
Chinese Journal of Light Scattering,1997,9(2-3), 292-294
30. Dependence of surfaceenhanced Raman scattering of 液態水 on the 氫 evolution reaction,
Chen Y. X. and Tian Z. Q.:
Chemical Physical Letters, 1997,281,379.
31. Raman spectroscopic studies of 液態水 in different electrolyte solutions.
Zou S. Z., Chen Y. X., Zhang Y. H., , Tian Z. Q. :
Acta PhysICOChimica Sinica 1996,12 (2) 130-135.
32. Probing electrode/electrolyte interfacial structure in the potential region of 氫 evolution by Raman spectroscopy.
Tian Z. Q., Ren B., Chen Y. X., Zou S. Z. and Mao B. W.:
Journal of Chemistry Society, Faraday Transactions ,1996,92(20) 3829-3838.
33. SERS studies of the structure and orientation of water over Ag electrode---the effects of electrode potentials and electrolyte concentration.
Zou S. Z., Zhang Y. H., Chen Y. X., Tian Z. Q.:
Chemical Journal of Chinese Universities 1995,16 (2), 245-251.
34. SERS effect induced from conducting Polymer/Solution Interfaces.
Gao J. S., Chen Y. X., Tian Z. Q., Li C. Z., Liu Z. F. and Cai S. M.:
Electrochemistry 1995, 1(2), 237-247.
35. Extending surfaceenhanced Raman spectroscopic studies on 液態水 at gold electrodes.
Tian Z. Q., Chen Y. X., Mao B. W., Li C. Z., Wang J. and Liu Z. F.
Chemical Physical Letters, 1995, 240, 224-229.
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