包明，男，畢業于東北大學，博士，現為大連理工大學精細化工國家重點實驗室教授、博士生導師。
人物經歷
教育經歷
工作經歷
1989.7—1997.10，碩士畢業后留校工作，歷任助教、講師。
2001.4—2002.10，日本產業技術綜合研究所特別研究員。
2002.11—2004.12，日本學術振興會(JSPS)特別研究員。
2005.1—現在，大連理工大學精細化工國家重點實驗室教授、博士生導師。
主要成就
科研成就
研究領域
金屬有機化學、有機合成化學、應用化學。
論文
（2000年以來的論文，SCI檢索）
1. Zhang, S.; Wang, Y.; Feng, X.; Bao, M., Palladium-Catalyzed Amination of Chloromethylnaphthalene and Chloromethylanthracene Derivatives with Various Amines. Journal of the American Chemical Society 2012, 134 (12), 5492–5495.
2. Dai, Y.; Feng, X.; Wang, B.; He, R.; Bao, M., Preparation and application of air-stable P,N-bidentate ligands for the selective synthesis of δ-lactone via the 鈀catalyzed telomerization of 1,3-butadiene with 碳 dioxide. Journal of Organometallic 化學 2012, 696, (26), 4309-4314.
3. Lu, S.; Jin, T.; Bao, M.; Yamamoto, Y., 鈷Catalyzed Hydroalkylation of Fullerene with Active Alkyl Bromides: Selective Synthesis of Monoalkylated Fullerenes. Journal of the American Chemical Society 2011, 133, (32), 12842-12848.
4. Lu, S.; Jin, T.; Kwon, E.; Bao, M.; Yamamoto, Y., Highly Efficient Cu(OAc)2-Catalyzed Dimerization of Monofunctionalized Hydrofullerenes Leading to Single-Bonded Fullerene Dimers. Angewandte Chemie International Edition 2011, 51, (3), 802-806.
5. Dai, Y.; Feng, X.; Liu, H.; Jiang, H.; Bao, M., Synthesis of 2-Naphthols via Carbonylative Stille Coupling Reaction of 2-Bromobenzyl Bromides with Tributylallylstannane Followed by the Heck Reaction. The Journal of Organic Chemistry 2011, 76, (24), 10068-10077.
6. Xu, Z.; Yu, X.; Feng, X.; Bao, M., Propargylamine Synthesis by 銅Catalyzed Oxidative 耦合 of Alkynes and Tertiary Amine N-Oxides. The Journal of Organic 化學 2011, 76, (16), 6901-6905.
7. Peng, B.; Zhang, S.; Yu, X.; Feng, X.; Bao, M., Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via η3-Benzylpalladium Intermediates: A New Strategy for 催化 Dearomatization. Organic Letters 2011, 13, (19), 5402-5405.
8. Feng, X.; Zhao, Z.; Yang, F.; Jin, T.; Ma, Y.; Bao, M., 1,3-Diynes synthesis by homo-coupling of terminal alkynes using a Pd(PPh3)4/氧化銀 simple catalyst system. Journal of Organometallic Chemistry 2011, 696, (7), 1479-1482.
9. Zhou, X.-Y.; Wang, D.-S.; Bao, M.; Zhou, Y.-G., Palladium-catalyzed asymmetric hydrogenation of simple ketones activated by Br?nsted acids. Tetrahedron Letters 2011, 52, (22), 2826-2829.
10. Zhou, X.-Y.; Bao, M.; Zhou, Y.-G., Palladium-Catalyzed Asymmetric Hydrogenation of Simple Ketimines Using a Br?nsted Acid as Activator. Advanced Synthesis & Catalysis 2011, 353, (1), 84-88.
11. Yang, F.; Jin, T.; Bao, M.; Yamamoto, Y., Facile synthesis of 3,4-dihalofurans via electrophilic iodocyclization. Chemical Communications 2011, 47, (15), 4541-4543.
12. Yang, F.; Jin, T.; Bao, M.; Yamamoto, Y., Facile synthesis of diiodinated dihydronaphthalenes and naphthalenes via 碘 mediated electrophilic cyclization. Chemical Communications 2011, 47, (13), 4013-4015.
13. Feng, X. J.; Yan, M.; Zhang, X.; Bao, M., Preparation and application of SBA-15-supported palladium catalyst for Heck reaction in supercritical carbon dioxide. Chinese Chemical Letters 2011, 22, (6), 643-646.
14. Yang, F.; Jin, T.; Bao, M.; Yamamoto, Y., Facile synthesis of 3,4-diiododihydrothiophenes via electrophilic iodocyclization. Tetrahedron Letters 2011, 52, (8), 936-938.
15. Dai, Y.; Liu, H.; Feng, X.; Bao, M., Preparation and Application of New P, N-Ligands for Palladium-Catalyzed C-N Bond Coupling Reaction. Chinese Journal of Catalysis 2011, 32, (10), 1617-1623.
16. Yu, X.; Ma, Y.; Zhao, Z.; Xu, Z.; Bao, M., Cross-Coupling Reaction of 芐型 Halides with Allyltributylstannane Catalyzed by Cu(OTf)(2). Chinese Journal of Catalysis 2011, 32, (3), 472-476.
17. Peng, B.; Feng, X.; Zhang, X.; Ji, L.; Bao, M., Regioselective control using a catalyst switch in the reaction of diarylmethyl chlorides with allyltributylstannane. Tetrahedron 2010, 66, (32), 6013-6018.
18. Liu, Y.; Feng, X. J.; Bao, D. C.; Li, K. X.; Bao, M., Preparation of microcapsule-supported palladium catalyst using SPG (Shirasu Porous Glass) emulsification technique. Chinese Chemical Letters 2010, 21, (8), 979-982.
19. Du, X.; Feng, X. J.; Liu, Y.; He, R.; Bao, M., Suzuki reaction of bromoallenes with arylboronic acids using an air-stable palladium complex Pd(Ph2PCH2CO2)2 as a precatalyst. Chinese Chemical Letters 2010, 21, (6), 641-645.
20. Liu, Y.; Feng, X.; Bao, D.; Li, K.; Bao, M., A new method for the preparation of microcapsule-supported palladium catalyst for Suzuki coupling reaction. Journal of Molecular Catalysis A: Chemical 2010, 323, (1-2), 16-22.
21. Peng, B.; Feng, X.; Zhang, X.; Zhang, S.; Bao, M., Propargylic and Allenic Carbocycle Synthesis through Palladium-Catalyzed Dearomatization Reaction. The Journal of Organic Chemistry 2010, 75, (8), 2619-2627.
22. Lu, S.; Jin, T.; Bao, M.; Yamamoto, Y., PalladiumCatalyzed Three-Component [3 + 2] Cycloaddition of Propargyl Trifluoroacetates, Ethylidene Malononitriles, and Allyltributylstannane. Organic Letters 2010, 12, (4), 864-866.
23. Feng, X.; Yan, M.; Zhang, T.; Liu, Y.; Bao, M., Preparation and application of SBA-15-supported palladium catalyst for Suzuki reaction in supercritical 碳 dioxide. Green 化學 2010, 12, (10), 1758-1766.
24. Zhou, L.; Du, X.; He, R.; Ci, Z.-H.; Bao, M. Nickel Salt-catalyzed Addition Reaction of Arylboronic Acids to Aromatic Aldehydes, Tetrahedron Lett. 2009, 50, 406–408.
25. Lu, S.-R.; Xu, Z.-W.; Bao, M.; Yamamoto, Y. Carbocycle Synthesis through Facile and Efficient Palladium-Catalyzed Allylative Dearomatization of Naphthyl- and Phenanthryl-Allyl Chlorides, Angew. Chem. Int. Ed. 2008, 47, 4366-4369.
26. Zhou, L.; Miao,Q.-Q.; He, R.; Feng, X.-J.; Bao, M. Ni-catalyzed Cross-Coupling Reaction of Aryl Chlorides with Arylboronic Acids in IPA without Using a Reducing 化學試劑, Tetrahedron Lett., 2007, 48, 7899-7902.
27. Du, X.; Dai, Y.; He, R.; Lu, S.-R.; Bao, M. A New Application of N- Halosuccinimide/PPh3 for the Halogenation of Propargyl Alcohols to Haloallenes, Synth. Commun. 2009, 39, (21), 3940-3949.
28. Zhou, L.; Feng, X.-J.; He, R.; Bao, M. X-ray Structure of trans-Chloro(1-naphthyl) bis(triphenylphosphane)鎳(II) and its Application for Catalytic Dehalogenation of Aryl Chlorides, J. Coord. Chem. 2009, 62, (17), 2824-2831.
29. Bao, M.; Hayashi, T.; Shimada, S. Cationic Organobismuth Complex with 5,6,7,12-Tetrahydrodibenz[c,f][1,5] azabismocine Framework and Its Coordination Complexes with Neutral Molecules, Organometallics, 2007, 26, 1816-1822.
30. Bao, M.; Shimizu, M.; Shimada, S; Inoue, J.; Konakahara, T. Reactions of N-Sulfenyl-1,2-benzisothiazolin-3-ones with Nucleophiles, Tetrahedron, 2004, 60, 11359-11366.
31. Bao, M.; Hayashi, T.; Shimada, S. Synthesis and Structural Characterization of a Cationic Trinuclear Organobismuth Complex with an Unprecedented Coordination Mode of Hydrotris(2-mercaptoimidazolyl)borate Ligands, Dalton Transactions, 2004, 2055-2056.
32. Bao, M.; Hatanaka, Y.; Shimada, S. The First Synthesis and X-ray Structure of [1.1]Silaferrocenophane Containing Pentacoordinate 硅 Moieties, Chem. Lett., 2004, 33 (5), 520-521.
33. Bao, M.; Shimizu, M. N-Trifluoroacetyl Arenesulfenamides, Efficient Precursors for Synthesis of Unsymmetrical Disulfides and Sulfenamides, Tetrahedron, 2003, 59, 9655-9659.
34. Bao, M.; Shimizu, M.; Shimada, S.; Tanaka, M. Efficient Synthesis of N-Acylarenesulfenamides by Acylation of Arenesulfenamides, Tetrahedron, 2003, 59, 303-309.
35. Bao, M.; Nakamura, H.; Inoue, A.; Yamamoto, Y. Nucleophilic Allylation-Heterocyclization via Bis-π-allylpalladium Complexes: Synthesis of Five- and Six-Membered Heterocycles, Chem. Lett., 2002, 2, 158-159.
36. Nakamura, H.; Bao, M.; Yamamoto, Y. The Fate of Bis(η3-allyl)鈀 Complexes in the Coexistence of Aldehydes (or Imines) and Allylic Chlorides. Stille Coupling versus Allylation of Aldehydes (or Imines), Angew. Chem. Int. Ed., 2001, 40, 3208-3210.
37. Bao, M.; Nakamura, H.; YAMAMOTO, Y. Facile Allylative Dearomatization Catalyzed by Palladium, J. Am. Chem. Soc., 2001, 123, 759-760.
38.Bao, M.; Nakamura, H.; Yamamoto, Y. Preparation and Application of Polymer-Supported Chiral π-allylpalladium Catalyst for the Allylation of Imines, Tetrahedron Lett., 2000, 41, 131-134.
39. 陸仕榮，彭勃，包明*，芳香族化合物的脫芳構化反應研究進展，化學進展, 2007, 19, 1529-1536.
40. 張濤，馮秀娟，王春霞，包明*，超臨界二氧化碳介質中鈀催化的一些交叉偶聯反應的研究，有機化學，2007, 27, 1463-1472.
鑒定成果
吉林省科委項目“有機錫新農藥的合成和生物活性的研究”，登記號: 96128-1，1996年10月，第一完成人。
專利成果
獲日本專利成果6項，申請中國專利5項。
教學成就
講授課程
本科課程：有機化學，有機化學實驗。
碩士研究生課程：有機合成化學，有機合成化學實驗。
博士研究生課程：工業催化過程化學與研究。
指導碩、博士生研究方向
有機合成方法學
(1)鈀催化脫芳構化反應及其在生物活性物質、功能材料合成中的應用。
(2)蘭尼鎳在氯代芳烴的偶聯反應、羰基化合物的加成反應及芳香鹵代烴的脫鹵反應中的活用。
(3)不對稱催化反應—將手性催化劑應用于本組發現的新有機反應。
(4)均相催化反應的復相化研究—微膠囊膜內負載過渡金屬催化劑，形成微催化反應環境。
(1)二氧化碳的催化活化及資源化利用—合成醫藥中間體、功能材料。
(2)超臨界二氧化碳介質中有機合成反應的研究。
社會活動
大連理工大學“分子的高效活化轉化與新物質創造”科研創新團隊成員、教育部“光轉化功能分子設計合成及應用”創新團隊成員、撫順精細化工應用技術研究院科技專家、中國化學會會員、中國化學會催化學會均相催化專業委員會委員。
獲得榮譽
參考資料 >
大連理工大學主頁平臺管理系統 包明--中文主頁--首頁.大連理工大學.2021-03-20