葉保輝,出生于1964年11月,畢業于中山大學,現任中山大學化學院無機化學與材料研究所教授。
1998年,葉保輝的“生物工程方法生產葡萄糖酸鋅(鎂、錳、內)新工藝的研究”獲國家教育部科技進步二等獎(發明類)。
人物經歷
1994年畢業于中山大學,獲博士學位:
1994年10月至1997年10月在香港科技大學作博士后,
1997年10月到中山大學工作,并聘為副教授,
1999年7月至2001年6月獲日本學術振興會(JSPS)資助在日本九州大學(Kyushu University)作博士后特別研究員。
講授課程
曾講授《無機與分析化學》、《應用無機化學》、《無機化學實驗》、《配位化學》等本科生、研究生課程。指導碩士研究生、協助指導博士研究生。
科研方向
功能金屬配位化合物超分子體系的分子設計、合成和結構與性能研究,重點在超分子配合物在催化、有機合成、分離、材料化學等領域中的應用。
主持項目
1.鐵(III)-銅(II)異核細胞色素C氧化酶的模擬研究(日本學術振興會)
2.仿生水解酶的模研究(廣東省自然科學基金)
3.手性配合物的識別及組裝(教育部)
主要論著
近年主要論著 (全部為SCI收錄)
1.Synthesis and Structural Characterization of Di- and Tetranuclear 鋅 Complexes with Phenolate and Carboxylate Bridges. Correlations between 13C NMR Chemical Shifts and Carboxylate Binding Modes,Bao-Hui Ye*, Xiao-Yuan Li, Ian D. Williams, Xiao-Ming Chen, Inorg. Chem. 2002, 41(24), 6426-6431
2. Interlocking of molecular rhombi into a 2D polyrotaxane network via p-p interactions. 晶體 structure of [Cu2(bpa)2(phen)2(H2O)2].2H2O (bpa2- = biphenyl-4,4'-dicarboxylate, phen = 1,10-phenanthroline). G.-F. Liu, B.-H, Ye, Y.-H. Liu, X.-M. Chen Chem. Commun. 2002, 1442-1443.
3. The 設計 of new molecular "light switches" for 脫氧核糖核酸, X.-H. 左姓, B.-H. Ye, H. Li, Q.-L. Zhang, H. Chao, J.-G. Liu, L.-N. Ji, X.-Y. Li, J. Biol. Inorg. Chem. 2001, 6, 143.
4. Enantiomeric ruthenium(II) complexes binding to DNA: binding modes and enantioselectivity, J.-G. Liu, B.-H. Ye, Q.-L. Zhang, X.-H. Zou, Q.-X. Zhen, X. Tian and L.-N. Ji, J. Biol. Inorg. Chem., 2000, 5(1), 119-128.
5. A novel m3-cyano-bridged hetreotrimetallic 2-D coordination polymer constructed from rectangular grids, H. Zhang, J. Cai, X.-L. Feng, BH Ye, X.-Y. Li, L.-N. Ji, J. Chem. Soc. Dalton Trans. 2000, 1687.
6. Three-dimensional coordination polymers self-assembled by unusual 配體unsupported Ag-Ag bonds. Syntheses, structures and luminescent properties of [Ag2(H2L)3]nX2n (H2L = 1,4-bis(salicyladeneamino)丁烷, X- = NO3- and ClO4-), M.-L. Tong, X.-M. Chen, B.-H. Ye and L.-N. Ji, Angew. Chem. Int. Ed. Engl. 1999, 38(15), 2237-2240 .
7. GIAO nuclear magnetic shielding tensors in free base 卟啉 and in 鎂 and 鋅 metalloporphyrins, P. M. Kozlowski, K. Volinski, P. Pulay, BH Ye and X.-Y. Li, J. Phy. Chem. A, 1999, 103(3), 420-425.
8. DFT-SQM force field for nickel porphine: intrinsic ruffling, P. M. Kozlowski, T. S. Rush III, A. A. Jarzecki, M. Z. Zgierski, B. Chase, C. Piffat, B.-H. Ye, X.-Y. Li, P. Pulay and T. G. Spiro, J. Phy. Chem. A, 1999, 103(10), 1357-1366.
9. Syntheses, characterization and third order non-linear optical properties of the ruthenium(II) complexes containing 2-phenyl-imidazo[4,5-f][1,10]phenanthroline derivatives, H, Chao, R-H. Li, B.-H. Ye, H. Li, X.-Long Feng, J.-W. Cai, J.-Y. Zhou and L.-N. Ji, J. Chem. Soc. Dalton Trans. 1999, 3711-3717.
10. Mono- and binuclear ruthenium(II) complexes containing a new asymmetric 配體 3-pyrazyl-強直性脊柱炎triazino[5,6-f]1,10-phenanthroline: Synthesis, Characterization and 脫氧核糖核酸binding properties, X.-H. Zou, B.-H. Ye, H Li, J.-G. Liu, Y. Xiong and L.-N. Ji, J. Chem. Soc. Dalton Trans. 1999, 1423-1428.
11. Clathration of Two-Dimensional Coordination Polymers: Synthesis and Structures of [M(4,4'-bpy)2(H2O)2](ClO4)2×(2,4'-bpy)2×H2O and [Cu(4,4'-bpy)2(H2O)2]](ClO4)4×(4,4'-H2bpy) (M=CdII, ZnII and bpy =bipyridine), M.-L. Tong, B.-H. Ye, J.-W. Cai, X.-M. Chen and S. W. Ng, Inorg. Chem. 1998, 37, 2645-2650.
12. Mononuclear Nickel Complexes Assembled into Two-dimensional Networks via 氫 Bonds and p-p Stacking interactions, B.-H. Ye, X.-M. Chen, G.-Q. Xue and L.-N. Ji, J. Chem. Soc. Dalton Trans. 1998, 2827-2827.
13. Helical Silver(I)-2,4'-bipyridine Chains Organized into 2-D Networks by Metal-counterion or Metal-metal Bonding. Structures of [Ag(2,4'-bipyridine)]X (X-= NO3- or ClO4-), M.-L. Tong, X.-M. Chen, BH Ye and S. W. Ng, Inorg. Chem. 1998, 37, 5278.
14. The First Two Aqua-bridged Dimagnesium(II) complexes: Structural Models for Active Sites in Dimetallic Hydrolases, B.-H. Ye, T. Mak, I. D. Willams and X.-Y. Li, J. Chem. Soc. Dalton Trans. 1998, 1935-1936.
15. Electronic Paramagnetic 共振 and Magnetic Properties of Model Complexes for Binuclear Active Sites in Hydrolase Enzymes, B. E. Schultz, BH Ye, X.-Y. Li. S. I. Chan, Inorg. Chem. 1997, 36(12), 2617-2622.
16. Novel Dimanganese(II) Complexes with (m-H2O)(m-OAc)2 Bridges. Model for Dimanganese Enzymes, B.-H. Ye, T. Mak, I. D. Williams and X.-Y. Li, Chem. Commun. 1997, 1813-1814.
17. Formation of a Novel Tetranuclear Iron(III) Complex with a m4-PO4 Bridge from 4-Nitrophenyl 磷酸鹽, B.-H. Ye, X.-Y. Li, F. Xue and T. C. W. Mak, Chem. Commun. 1997, 2407-2408.
18. Bis(2,2'-bipyridine)ruthenium(II) Complexes with Imidazo[4,5-f][1,10]phenanthroline or 2-phenylimidazo[4,5-f][1,10]phenanthroline, J.-Z. Wu, B.-H. Ye, L. Wang, L-N. Ji, J.-Y. Zhou, R-H. Li, Z.-Y. Zhou, J. Chem. Soc. Dalton Trans. 1997, 1395-1401.
獲獎情況
1.1996年“混配配合物的生物功能、作用機制及其應用探索”1996年獲廣東省自然科學一等獎。(第三完成人)
2.1998年“金屬酶體系的結構、機制和模擬研究”獲國家教育部科技進步二等獎(基礎類)。(第三完成人)
3.1998年“生物工程方法生產葡萄糖酸鋅(鎂、錳、內酯)新工藝的研究”獲國家教育部科技進步二等獎(發明類)。
4.1998年“含羧基與多胺基的金屬酶模型化合物的研究”獲廣東省自然科學一等獎。
5.200年“金屬酶模型化合物的結構、生物功能、作用機制之間規律性”獲中國高校自然科學二等獎。(第四完成人)
獲專利情況:
1994年“黑曲酶發酵生產葡萄糖酸鋅”獲國家知識產權局發明專利,1996年3月27日公開,公開號:CN119213A。
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